Triphenyl phosphite → HCID 20551081, compound

HRID 1833972Notes

Reaction equation

HRID 1833972 reaction equation
[CH:1]1[C:10]2[C:5](=[CH:6][CH:7]=CC=2)[CH:4]=[CH:3][C:2]=1O.P(OC1C=CC=CC=1)(OC1C=CC=CC=1)O[C:14]1C=CC=C[CH:15]=1.[CH2:34]([NH2:47])[CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH3:46]>O>[CH2:36]([C:35]1[CH:7]=[CH:6][C:5]2[C:4](=[CH:3][CH:2]=[CH:1][CH:10]=2)[C:34]=1[NH2:47])[CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:14][CH3:15]

Participants

5

Reactant 3

HCID 7540Triphenyl phosphiteHCID 86632-NaphtholHCID 40761Tridecylamine

Product 1

HCID 20551081HCID 20551081, compoundYield 97%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

288 parts of β-naphthol, 9 parts of triphenyl phosphite and 418 parts of tridecylamine are heated to 175° C, whilst stirring. The elimination of water commences at this temperature and has ended after 10 hours, when the internal temperature is 230° C and 36 parts of water have been removed. Excess β-naphthol and amine are distilled off in vacuo. 2-Tridecyl-naphthylamine is then distilled at a boiling point of 225° C/3 mm Hg. 630 parts of end product are obtained, corresponding to a yield of 97% of theory.

Workup

  1. customis 230° C
  2. custom36 parts of water have been removed
  3. distillationExcess β-naphthol and amine are distilled off in vacuo
  4. distillation2-Tridecyl-naphthylamine is then distilled at a boiling point of 225° C/3 mm Hg
  5. custom630 parts of end product are obtained, corresponding to a yield of 97% of theory

Sources & evidence

ORD record
ord-87e8895699944a8d9bca7ee0f150f969
Source dataset
uspto-grants-1978_01
Patent number
US04067903

Reaction notes

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