Aluminum isopropoxide → HCID 14691048, compound

HRID 1834167Notes

Reaction equation

HRID 1834167 reaction equation
[CH3:1][C:2]1[CH2:6][CH2:5][CH:4]([C:7]([CH3:9])=[CH2:8])[C:3]=1[CH2:10][C:11]([CH3:15])([CH3:14])[CH:12]=[O:13].CC([O-])C.CC([O-])C.CC([O-])C.[Al+3]>C(O)(C)C>[CH3:1][C:2]1[CH2:6][CH2:5][CH:4]([C:7]([CH3:9])=[CH2:8])[C:3]=1[CH2:10][C:11]([CH3:15])([CH3:14])[CH2:12][OH:13]

Participants

4

Reactant 2

HCID 11143Aluminum isopropoxideHCID 50142621-Methyl-2-(2,2-dimethyl-2-formylethyl)-3-isopropenylcyclopent-1-ene

Product 1

HCID 14691048HCID 14691048, compound

Reagents, catalysts & solvents 1

HCID 3776IsopropanolSolvent

Procedure

103 g (0.5 mole) of the product from Example 1 were reduced with 60 g of isopropanol and 20 g of aluminum triisopropylate by the Meerwein-Ponndorf method. The conversion was 78% and the yield of the above compound (for characteristics thereof, see Example 3), based on the above conversion, was 73%.

Sources & evidence

ORD record
ord-93ca427e89314dd5bef9a8e4295c5a51
Source dataset
uspto-grants-1978_01
Patent number
US04069258

Reaction notes

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