HRID1835016

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID6547

Azobisisobutyronitrile

C8H12N4

HCID7923

2,5-Furandione

C4H2O3

HCID78949

Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid

C8H10O2

HCID12033823

2-Hydroxyethyl bicyclo[2.2.1]hept-5-ene-2-carboxylate

C10H14O3

HCID15607334

Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, 1,1-dimethylethyl ester

C12H18O2

PRODUCTS

生成物

结构：CC(C)(C)OC(=O)C1CC2C=CC1C2.O=C(O)C1CC2C=CC1C2.O=C(OCCO)C1CC2C=CC1C2.O=C1C=CC(=O)O1

HCID86593317

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID1140

Toluene

C7H8

溶剂HCID8028

Tetrahydrofuran

C4H8O

PROCEDURE

实验过程

To tetrahydrofuran or toluene was added 0.5 to 0.95 mole of tert-butyl 5-norbornene-2-carboxylate, 0.05 to 0.8 mole of 2-hydroxyethyl 5-norbornene-2-carboxylate, 0.01 to 0.2 mole of 5-norbornene-2-carboxylic acid, 0.5 to 1 mole of maleic anhydride and 0.5 to 10 g of 2,2′-azobisisobutyronitrile (AIBN).

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-1242273c413c47669351e37260db5353
来源数据集: uspto-grants-2004_08
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06770414B2
来源说明: uspto-grants-2004_08

反应 SMILES

[CH:1]12[CH2:7][CH:4]([CH:5]=[CH:6]1)[CH2:3][CH:2]2[C:8]([O:10][C:11]([CH3:14])([CH3:13])[CH3:12])=[O:9].[CH:15]12[CH2:21][CH:18]([CH:19]=[CH:20]1)[CH2:17][CH:16]2[C:22]([O:24][CH2:25][CH2:26][OH:27])=[O:23].[CH:28]12[CH2:34][CH:31]([CH:32]=[CH:33]1)[CH2:30][CH:29]2[C:35]([OH:37])=[O:36].[C:38]1(=[O:44])[O:43][C:41](=[O:42])[CH:40]=[CH:39]1.N(C(C)(C)C#N)=NC(C)(C)C#N>C1(C)C=CC=CC=1.O1CCCC1>[CH:1]12[CH2:7][CH:4]([CH:5]=[CH:6]1)[CH2:3][CH:2]2[C:8]([O:10][C:11]([CH3:14])([CH3:13])[CH3:12])=[O:9].[CH:15]12[CH2:21][CH:18]([CH:19]=[CH:20]1)[CH2:17][CH:16]2[C:22]([O:24][CH2:25][CH2:26][OH:27])=[O:23].[CH:28]12[CH2:34][CH:31]([CH:32]=[CH:33]1)[CH2:30][CH:29]2[C:35]([OH:37])=[O:36].[C:41]1(=[O:42])[O:43][C:38](=[O:44])[CH:39]=[CH:40]1