Hydrogen Peroxide → Phosphoric acid--trioxotungsten--water (1/12/1)

HRID 1855105Notes

Reaction equation

HRID 1855105 reaction equation
[O-:1][W:2]([O-])(=[O:4])=[O:3].[Na+].[Na+].[P:8](=[O:12])([OH:11])([OH:10])[OH:9].S(=O)(=O)(O)O.OO>O.[Cl-].C([N+](CCCC)(CCCC)CCCC)CCC>[OH2:1].[OH:10][P:8]([OH:12])([OH:11])=[O:9].[O:1]=[W:2](=[O:4])=[O:3].[O:1]=[W:2](=[O:4])=[O:3].[O:1]=[W:2](=[O:4])=[O:3].[O:1]=[W:2](=[O:4])=[O:3].[O:1]=[W:2](=[O:4])=[O:3].[O:1]=[W:2](=[O:4])=[O:3].[O:1]=[W:2](=[O:4])=[O:3].[O:1]=[W:2](=[O:4])=[O:3].[O:1]=[W:2](=[O:4])=[O:3].[O:1]=[W:2](=[O:4])=[O:3].[O:1]=[W:2](=[O:4])=[O:3].[O:1]=[W:2](=[O:4])=[O:3]

Participants

7

Reactant 4

HCID 784Hydrogen PeroxideHCID 1004Phosphoric AcidHCID 1118Sulfuric AcidHCID 26052Sodium tungstate

Product 1

HCID 16212977Phosphoric acid--trioxotungsten--water (1/12/1)

Reagents, catalysts & solvents 2

HCID 70681Tetrabutylammonium ChlorideCatalystHCID 962WaterSolvent

Procedure

For example, by dissolving sodium tungstate (VI) in distilled water, adding an aqueous solution of phosphoric acid to the obtained solution, and then adding concentrated sulfuric acid to adjust the pH to an acidic range, followed by addition of hydrogen peroxide, stirring at room temperature, and then, adding a halogenated quaternary ammonium such as tetra-(n-butyl)ammonium chloride, it is possible to obtain the tungstophosphoric acid salt represented by the formula (3) such as tri[tetra-(n-butyl)ammonium]tetra(diperoxotungsto)phosphoric acid salt.

Sources & evidence

ORD record
ord-8780dd28b5334e91aa5605de0028c7d6
Source dataset
uspto-grants-2015_02
Patent number
US08962849B2

Reaction notes

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