反应详情

Nine grams of the product as prepared in Example XXIII, i.e. tetrasodium propene-1,1,2,3-tetracarboxylate, is dissolved in 100 mls water and acidified with dilute HCl (10%). Liberation of CO2 is instantaneous. The residue, after evaporation of water, is extracted with acetone. The acetone is evaporated to leave a residue consisting of a 1:1 by weight mixture of cis:trans aconitric acid. The structure of the product is confirmed by NMR analysis (D2O): ##STR77##

1. customThe residue, after evaporation of water
2. extractionis extracted with acetone
3. customThe acetone is evaporated
4. customto leave a residue
5. additionconsisting of a 1:1 by weight mixture of cis