Methanol → HCID 54408349, compound

HRID 1856502Notes

Reaction equation

HRID 1856502 reaction equation
[N+:1]([CH:4]=[C:5]([CH3:8])[CH:6]=[CH2:7])([O-:3])=[O:2].[Na].[CH3:10][OH:11]>>[N+:1]([CH2:4][C:5]([CH3:8])=[CH:6][CH2:7][O:11][CH3:10])([O-:3])=[O:2]

Participants

4

Reactant 3

HCID 887MethanolHCID 5360545SodiumHCID 54297158HCID 54297158, compound

Product 1

HCID 54408349HCID 54408349, compound

Procedure

0.1 Mol of 1-nitro-2-methyl-1,3-butadiene was added to a solution of 0.1 Mol of sodium in methanol and stirred overnight. The reaction mixture was quenched in ice and extracted with methylene chloride. The oily residue was purified via column chromatography. The product was obtained as a yellow liquid.

Workup

  1. customThe reaction mixture was quenched in ice
  2. extractionextracted with methylene chloride
  3. customThe oily residue was purified via column chromatography
  4. customThe product was obtained as a yellow liquid

Sources & evidence

ORD record
ord-e246feaff8524aada86d486c4a2351d3
Source dataset
uspto-grants-1980_08
Patent number
US04219660

Reaction notes

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