Chloride → n-Octylsuccinyl dichloride

HRID 1856542Notes

Reaction equation

HRID 1856542 reaction equation
[CH2:1]([CH:9]1[CH2:14][C:13](=[O:15])O[C:10]1=[O:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].P(Cl)(Cl)(Cl)(Cl)[Cl:17].[Cl-:22]>>[CH2:1]([CH:9]([CH2:14][C:13]([Cl:17])=[O:15])[C:10]([Cl:22])=[O:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]

Participants

4

Reactant 3

HCID 312ChlorideHCID 24819Phosphorus pentachlorideHCID 778692,5-Furandione, dihydro-3-octyl-

Product 1

HCID 23345517n-Octylsuccinyl dichlorideYield 79.2%

Procedure

n-Octylsuccinyl dichloride was prepared by reacting n-octylsuccinic anhydride with PCl5 at 105°-110° C. for about four hours. After working the product up 101.3 g of liquid was obtained which had a purity of 84.3% according to chloride content. The corrected yield was 79.2%.

Workup

  1. customat 105°-110° C.
  2. customfor about four hours
  3. customwas obtained which

Sources & evidence

ORD record
ord-7a5f942dfdec4f5b9ca667a9f9c5440c
Source dataset
uspto-grants-1980_08
Patent number
US04219676

Reaction notes

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