Bisphenol A diglycidyl ether → HCID 20393558, compound

HRID 1862920Notes

Reaction equation

HRID 1862920 reaction equation
[NH2:1][CH:2]1[CH2:7][C:6]([CH3:9])([CH3:8])[N:5]([CH3:10])[C:4]([CH3:12])([CH3:11])[CH2:3]1.[O:13]1[CH2:37][CH:14]1[CH2:15][O:16][C:17]1[CH:22]=[CH:21][C:20]([C:23]([C:26]2[CH:31]=[CH:30][C:29]([O:32][CH2:33][CH:34]3[O:36][CH2:35]3)=[CH:28][CH:27]=2)([CH3:25])[CH3:24])=[CH:19][CH:18]=1>CO>[OH:13][CH:14]([CH2:37][NH:1][CH:2]1[CH2:3][C:4]([CH3:11])([CH3:12])[N:5]([CH3:10])[C:6]([CH3:9])([CH3:8])[CH2:7]1)[CH2:15][O:16][C:17]1[CH:22]=[CH:21][C:20]([C:23]([C:26]2[CH:31]=[CH:30][C:29]([O:32][CH2:33][CH:34]([OH:36])[CH2:35][NH:1][CH:2]3[CH2:3][C:4]([CH3:12])([CH3:11])[N:5]([CH3:10])[C:6]([CH3:8])([CH3:9])[CH2:7]3)=[CH:28][CH:27]=2)([CH3:24])[CH3:25])=[CH:19][CH:18]=1

Participants

4

Reactant 2

HCID 2286Bisphenol A diglycidyl etherHCID 6937924-Amino-1,2,2,6,6-pentamethylpiperidine

Product 1

HCID 20393558HCID 20393558, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

To 100 ml of methanol were added 12 g of 4-amino-1,2,2,6,6-pentamethylpiperidine and 11 g of 2,2-bis[p-(2,3-epoxypropoxy)phenyl]propane; the mixture was then reacted in a similar manner to that described in Example 1, giving the desired compound in the form of white crystals melting at 141°-143° C. The compound had an Rf value of 0.64 on thin layer chromatography on silica gel developed with a 1:3:1 by volume mixture of methanol, ethyl acetate and triethylamine.

Workup

  1. customthe mixture was then reacted in a similar manner to that

Sources & evidence

ORD record
ord-4d00d188fb9d4d29be2cde2285d8b9d1
Source dataset
uspto-grants-1979_09
Patent number
US04166813

Reaction notes

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