Ethanol → HCID 54026503, compound

HRID 1863243Notes

Reaction equation

HRID 1863243 reaction equation
Br[C:2]12[CH2:11][CH:7]([CH2:8][CH2:9][CH2:10]1)[CH:6]1[CH2:12][CH:3]2[CH2:4][CH2:5]1.[CH2:13]([OH:15])[CH3:14]>[Ag]=O>[CH2:13]([O:15][C:2]12[CH2:11][CH:7]([CH2:8][CH2:9][CH2:10]1)[CH:6]1[CH2:12][CH:3]2[CH2:4][CH2:5]1)[CH3:14]

Participants

4

Reactant 2

HCID 702EthanolHCID 53870913HCID 53870913, compound

Product 1

HCID 54026503HCID 54026503, compoundYield 82.6%

Reagents, catalysts & solvents 1

HCID 92152Silver(II) oxideCatalyst

Procedure

A mixture of 5.0 g of 1-bromotricyclo[4.3.1.12,5 ]undecane, 3.0 g of silver oxide and 30 ml of anhydrous ethanol was refluxed for 2 hours. Thereafter, the mixture was treated in the same manner as described in Example 1 to obtain 3.5 g (yield, 82.6%) of 1-ethoxytricyclo[4.3.1.12,5 ]undecane having a boiling point of 97° to 98° C./4 mmHg.

Workup

  1. temperaturewas refluxed for 2 hours
  2. additionThereafter, the mixture was treated in the same manner

Sources & evidence

ORD record
ord-9946ae2a1de5456388350768be1db056
Source dataset
uspto-grants-1979_09
Patent number
US04168389

Reaction notes

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