1-Butanol → HCID 54230553, compound

HRID 1863244Notes

Reaction equation

HRID 1863244 reaction equation
Br[C:2]12[CH2:11][CH:7]([CH2:8][CH2:9][CH2:10]1)[CH:6]1[CH2:12][CH:3]2[CH2:4][CH2:5]1.[CH2:13]([OH:17])[CH2:14][CH2:15][CH3:16]>[Ag]=O>[CH2:13]([O:17][C:2]12[CH2:11][CH:7]([CH2:8][CH2:9][CH2:10]1)[CH:6]1[CH2:12][CH:3]2[CH2:4][CH2:5]1)[CH2:14][CH2:15][CH3:16]

Participants

4

Reactant 2

HCID 2631-ButanolHCID 53870913HCID 53870913, compound

Product 1

HCID 54230553HCID 54230553, compoundYield 65.3%

Reagents, catalysts & solvents 1

HCID 92152Silver(II) oxideCatalyst

Procedure

A mixture of 3.0 g of 1-bromotricyclo[4.3.1.12,5 ]undecane, 2.0 g of silver oxide and 30 ml of anhydrous n-butanol was refluxed for 6 hours. Thereafter, the mixture was treated in the same manner as described in Example 1, and there was obtained 1.9 g (yield, 65.3%) of 1-n-butoxytricyclo[4.3.1.12,5 ]undecane having a boiling point of 97° to 98° C./1 mmHg.

Workup

  1. temperaturewas refluxed for 6 hours
  2. additionThereafter, the mixture was treated in the same manner

Sources & evidence

ORD record
ord-12399872208345199112f99374286035
Source dataset
uspto-grants-1979_09
Patent number
US04168389

Reaction notes

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