Potassium Carbonate → HCID 86613084, compound

HRID 1869144Notes

Reaction equation

HRID 1869144 reaction equation
[Cl:1][C:2]1[CH:7]=[C:6]([O:8][CH2:9][CH:10]=[C:11]([Cl:13])[Cl:12])[CH:5]=[C:4]([Cl:14])[C:3]=1[OH:15].C(=O)([O-])[O-].[K+].[K+].[Cl:22][CH2:23][C:24]([CH2:26]Cl)=[CH2:25]>C(#N)C>[Cl:1][C:2]1[CH:7]=[C:6]([O:8][CH2:9][CH:10]=[C:11]([Cl:13])[Cl:12])[CH:5]=[C:4]([Cl:14])[C:3]=1[O:15][CH2:26][C:24]([CH2:23][Cl:22])=[CH2:25]

Participants

5

Reactant 3

HCID 11430Potassium CarbonateHCID 158593-Chloro-2-chloromethyl-1-propeneHCID 113467384-(3,3-Dichloro-2-propenyloxy)-2,6-dichlorophenol

Product 1

HCID 86613084HCID 86613084, compound

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Conditions

Temperature
80 °C

Procedure

20 g of 2,6-dichloro-4-(3,3-dichloro-allyloxy)-phenol and 28.8 g of potassium carbonate are introduced into 150 ml of acetonitrile. 26 g of 3-chloro-2-chloromethyl-propene are then added and the mixture is stirred for 2.5 hours at 80° C. The reaction mixture is cooled to room temperature and filtered, and the filtrate is concentrated. After purification over silica gel, 1,3-dichloro-2-(2-chloromethyl-allyloxy)-5-(3,3-dichloro-allyloxy)-benzene is obtained.

Workup

  1. temperatureThe reaction mixture is cooled to room temperature
  2. filtrationfiltered
  3. concentrationthe filtrate is concentrated
  4. customAfter purification over silica gel

Sources & evidence

ORD record
ord-be3c6a7c067d49e5b5638545b72596bc
Source dataset
uspto-grants-2009_12
Patent number
US07638514B2

Reaction notes

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