Ethylamine → HCID 86750054, compound

HRID 1870799Notes

Reaction equation

HRID 1870799 reaction equation
[N:1]1[CH:6]=[CH:5][CH:4]=[C:3](C=O)[CH:2]=1.[CH2:9]([NH2:11])[CH3:10]>C(Cl)(Cl)Cl>[N:1]1[CH2:2][C:3](=[N:11][CH2:9][CH3:10])[CH:4]=[CH:5][CH:6]=1

Participants

4

Reactant 2

HCID 6341EthylamineHCID 103713-Pyridinecarboxaldehyde

Product 1

HCID 86750054HCID 86750054, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

A solution of 3-pyridinecarboxaldehyde (1 g, 9.3 mmol) and ethylamine (661 mg, 10.2 mmol, 70% wt in water) was stirred at room temperature for 18 h. The reaction mixture was diluted with chloroform (20 mL) and dried over anhydrous K2CO3. The solution was filtered and the solvent was evaporated to afford N-(3-pyridylidene)-ethylamine (XVII). 1.15 g (92%), which was used immediately without further purification.

Workup

  1. dry with materialdried over anhydrous K2CO3
  2. filtrationThe solution was filtered
  3. customthe solvent was evaporated

Sources & evidence

ORD record
ord-0014fcd27b62469ba6f63acc6effbd13
Source dataset
uspto-grants-2000_08
Patent number
US06100269

Reaction notes

Loading…