1-Nonanol → Nonanal

HRID 1872447Notes

Reaction equation

HRID 1872447 reaction equation
[CH2:1]([OH:10])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9]>[Rh]>[CH:1](=[O:10])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9]

Participants

3

Reactant 1

HCID 89141-Nonanol

Product 1

HCID 31289NonanalYield 66%

Reagents, catalysts & solvents 1

HCID 23948RhodiumCatalyst

Procedure

Repetition of step 1 (12 ppm of Rh), rhodium catalyst/bottoms solution from (b) being used. A conversion of octenes of 99% and a yield of 66% nonanal and 15% nonanol were obtained at a 16% balance loss (based on octene-N: mechanical losses, formation of high-boilers and paraffin included).

Sources & evidence

ORD record
ord-a6b593d4a8a242ddb413e4b258375b8c
Source dataset
uspto-grants-2000_08
Patent number
US06107524

Reaction notes

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