Dimethylformamide → HCID 67094308, compound

HRID 1881188Notes

Reaction equation

HRID 1881188 reaction equation
[CH2:1]([O:3][C:4]1[C:11]([O:12][CH2:13][CH3:14])=[CH:10][C:7]([CH:8]=O)=[C:6]([N+]([O-])=O)[C:5]=1[N+:18]([O-:20])=[O:19])[CH3:2].[CH3:21]N(C)C=O.C[CH:27]([SH:31])[C:28]([O-:30])=[O:29]>C(N(CC)CC)C>[CH3:21][O:30][C:28]([C:27]1[S:31][C:6]2[C:5]([N+:18]([O-:20])=[O:19])=[C:4]([O:3][CH2:1][CH3:2])[C:11]([O:12][CH2:13][CH3:14])=[CH:10][C:7]=2[CH:8]=1)=[O:29]

Participants

5

Reactant 3

HCID 6228DimethylformamideHCID 156077362-MercaptopropionateHCID 86633441HCID 86633441, compound

Product 1

HCID 67094308HCID 67094308, compound

Reagents, catalysts & solvents 1

HCID 8471TriethylamineSolvent

Procedure

4,5-Diethoxy-2,3-dinitro-benzaldehyde (1.53 g) was dissolved into N,N-dimethylformamide (6 ml) and then methylthioglycolate (1.36 ml) was added. Triethylamine (2.6 ml) was added in cold to the reaction solution. The mixture was stirred overnight. The solid was filtered and washed with N,N-dimethylformamide.

Workup

  1. filtrationThe solid was filtered
  2. washwashed with N,N-dimethylformamide

Sources & evidence

ORD record
ord-091b2d51415b43bf900a177f8eefff47
Source dataset
uspto-grants-2012_11
Patent number
US08318785B2

Reaction notes

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