palladium(II) acetate → Palladium

HRID 1882294Notes

Reaction equation

HRID 1882294 reaction equation
CC([O-])=O.CC([O-])=O.[Pd+2:9].[CH:10]1([P:16]([CH:33]2[CH2:38][CH2:37][CH2:36][CH2:35][CH2:34]2)[C:17]2[CH:22]=[CH:21][CH:20]=[CH:19][C:18]=2[C:23]2[C:28]([O:29][CH3:30])=[CH:27][CH:26]=[CH:25][C:24]=2[O:31][CH3:32])[CH2:15][CH2:14][CH2:13][CH2:12][CH2:11]1>C1(C)C=CC=CC=1>[CH:33]1([P:16]([CH:10]2[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15]2)[C:17]2[CH:22]=[CH:21][CH:20]=[CH:19][C:18]=2[C:23]2[C:28]([O:29][CH3:30])=[CH:27][CH:26]=[CH:25][C:24]=2[O:31][CH3:32])[CH2:38][CH2:37][CH2:36][CH2:35][CH2:34]1.[Pd:9]

Participants

5

Reactant 2

HCID 167845palladium(II) acetateHCID 112698722-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl

Product 2

HCID 23938PalladiumHCID 112698722-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent2×

Conditions

Temperature
23 °C

Procedure

A solution of the catalyst was prepared as follows: An oven-dried Wheaton vial equipped with a magnetic stir bar was charged with Pd(OAc)2 (5.60 mg, 0.025 mmol, 1.0 eq.) and 2-dicyclohexylphosphino-2′,6′-dimethoxy-1,1′-biphenyl (4d) (20.5 mg, 0.050 mmol, 2.0 eq.). Toluene (3.00 mL) was added and the vial was sealed with a PTFE-lined plastic cap. The resulting mixture was stirred at 23° C. for 45 min. resulting in a yellow Pd/4d catalyst solution (0.00833 N Pd in toluene).

Workup

  1. customA solution of the catalyst was prepared
  2. customAn oven-dried Wheaton vial equipped with a magnetic stir bar

Sources & evidence

ORD record
ord-7d12a9a141e041bea9bd0267f22555fa
Source dataset
uspto-grants-2012_11
Patent number
US08318983B2

Reaction notes

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