Water → HCID 86084132, compound

HRID 1882351Notes

Reaction equation

HRID 1882351 reaction equation
[CH:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][C:2]=1[C:11]1[C:24]2[C:25]3=[C:26]4[C:21](=[CH:22][CH:23]=2)[CH:20]=[CH:19][C:18]([C:27]2[CH:36]=[CH:35][C:34]5[C:29](=[CH:30][CH:31]=[CH:32][CH:33]=5)[CH:28]=2)=[C:17]4[CH:16]=[CH:15][C:14]3=[C:13]([C:37]2[CH:42]=[CH:41][CH:40]=[CH:39][CH:38]=2)[CH:12]=1.C1C(=O)N([Br:50])C(=O)C1.O>CN(C=O)C>[Br:50][C:20]1[C:21]2[C:26]3=[C:25]4[C:24](=[CH:23][CH:22]=2)[C:11]([C:2]2[CH:3]=[CH:4][C:5]5[C:10](=[CH:9][CH:8]=[CH:7][CH:6]=5)[CH:1]=2)=[CH:12][C:13]([C:37]2[CH:38]=[CH:39][CH:40]=[CH:41][CH:42]=2)=[C:14]4[CH:15]=[CH:16][C:17]3=[C:18]([C:27]2[CH:36]=[CH:35][C:34]3[C:29](=[CH:30][CH:31]=[CH:32][CH:33]=3)[CH:28]=2)[CH:19]=1

Participants

5

Reactant 3

HCID 962WaterHCID 67184N-bromobutanimideHCID 86084129HCID 86084129, compound

Product 1

HCID 86084132HCID 86084132, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent2×

Procedure

5.4 g of 1,6-dinaphthalene-2-yl-3-phenylpyrene was dispersed into 60 ml of DMF, and 1.9 g NBS in DMF solution was dropped therein at room temperature. After 3 days reaction, 150 ml of water was added to it and the deposited crystal was filtrated, followed by water and ethanol washing of the crystal.

Workup

  1. additionwas dropped
  2. customat room temperature
  3. additionwas added to it
  4. filtrationthe deposited crystal was filtrated
  5. washwashing of the crystal

Sources & evidence

ORD record
ord-98ad62204d5f408e9c67bf99d51f494a
Source dataset
uspto-grants-2012_11
Patent number
US08318995B2

Reaction notes

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