N-vinyl-2-pyrrolidone → 1,3,5-Trimethoxybenzene

HRID 1882686Notes

Reaction equation

HRID 1882686 reaction equation
C=CN1CCCC1=O.Ic1ccccc1>Cc1cc(C)c(-n2cc[n+](-c3c(C)cc(C)cc3C)c2)c(C)c1.[Cl-].CC(C)(C)[O-].[K+].CCN(CC)CC.Cc1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.[Pd].[Pd]>COc1cc(OC)cc(OC)c1.O=C1CCCN1/C=C/c1ccccc1.C=C(c1ccccc1)N1CCCC1=O

Participants

10

Reactant 2

HCID 6917N-vinyl-2-pyrrolidoneHCID 11575Iodobenzene

Product 3

HCID 693011,3,5-TrimethoxybenzeneHCID 5371898HCID 5371898, compoundHCID 110196022-Pyrrolidinone, 1-(1-phenylethenyl)-

Reagents, catalysts & solvents 5

HCID 8471TriethylamineReagentHCID 27342111,3-Bis(2,4,6-trimethylphenyl)imidazolium chlorideCatalystHCID 23665647Potassium tert-butoxideCatalystHCID 1140TolueneSolventHCID 9811564Bis(dibenzylideneacetone)palladiumOther

Conditions

Temperature
85 °C

Workup

  1. additionKeep Filtrate

Sources & evidence

ORD record
ord-fd051541fff54635bb68a780e3f95746
Source dataset
N-vinyl pyrrolidone Mizoroki-Heck

Reaction notes

Loading…