Perchloric Acid → HCID 86644016, compound

HRID 1889210Notes

Reaction equation

HRID 1889210 reaction equation
[Cl:1]([OH:5])(=[O:4])(=[O:3])=[O:2].[CH:6]1([P:12]([CH:19]2[CH2:24][CH2:23][CH2:22][CH2:21][CH2:20]2)[CH:13]2[CH2:18][CH2:17][CH2:16][CH2:15][CH2:14]2)[CH2:11][CH2:10][CH2:9][CH2:8][CH2:7]1>C(OCC)C>[Cl:1]([O-:5])(=[O:4])(=[O:3])=[O:2].[CH:19]1([PH+:12]([CH:6]2[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11]2)[CH:13]2[CH2:18][CH2:17][CH2:16][CH2:15][CH2:14]2)[CH2:20][CH2:21][CH2:22][CH2:23][CH2:24]1

Participants

4

Reactant 2

HCID 24247Perchloric AcidHCID 75806Tricyclohexylphosphine

Product 1

HCID 86644016HCID 86644016, compoundYield 74.4%

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

1.1 ml (12 mmol) perchloric acid is added to 25 ml of a solution of 12 mmol tricyclohexyl phosphine in diethylether prepared as in comparative example 3. Under a slight heat development a crystalline solid precipitates immediately, which is filtered off, and washed with diethylether. 3.4 g of a colorless solid is obtained. This solid is an explosive due to a shock sensitivity at an impact energy of 25 J.

Workup

  1. customUnder a slight heat development a crystalline solid precipitates immediately
  2. filtrationwhich is filtered off
  3. washwashed with diethylether

Sources & evidence

ORD record
ord-e23c3a22a4ad459c9d3125fb098d42e7
Source dataset
uspto-grants-2013_08
Patent number
US08501985B2

Reaction notes

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