11-Aminoundecanoic acid → N,N,N-Trimethylmethanaminium 11-aminoundecanoate

HRID 1893120Notes

Reaction equation

HRID 1893120 reaction equation
[NH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]([OH:14])=[O:13].[OH-].[CH3:16][N+:17]([CH3:20])([CH3:19])[CH3:18]>O1CCCC1>[NH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]([O-:14])=[O:13].[CH3:16][N+:17]([CH3:20])([CH3:19])[CH3:18]

Participants

4

Reactant 2

HCID 1708311-Aminoundecanoic acidHCID 60966Tetramethylammonium hydroxide

Product 1

HCID 16212873N,N,N-Trimethylmethanaminium 11-aminoundecanoate

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

Tetramethylammonium 11-aminoundecanoate was synthesized by titration of a methanolic suspension of 11-aminoundecanoic acid (4.04 grams (g) in approximately 4 ml methanol, Aldrich) with methanolic tetramethylammonium hydroxide (8.4 ml, Aldrich), evaporation of the solvent under reduced pressure, and recrystallization from tetrahydrofuran (about 50 ml, Aldrich).

Sources & evidence

ORD record
ord-18781f1e58f548db8c82f63860fdca8d
Source dataset
uspto-grants-2013_08
Patent number
US08512946B2

Reaction notes

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