Methyl iodide → HCID 88282627, compound

HRID 1900217Notes

Reaction equation

HRID 1900217 reaction equation
[OH:1][N:2]=[CH:3][C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[CH2:10][C:11]([OH:13])=[O:12].IC.[C:16](=O)([O-])[O-].[K+].[K+].C([N+](CC)(CC)CC1C=CC=CC=1)C>C(#N)C>[CH3:16][O:1]/[N:2]=[CH:3]/[C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[CH2:10][C:11]([OH:13])=[O:12]

Participants

6

Reactant 4

HCID 6328Methyl iodideHCID 11430Potassium CarbonateHCID 17208BenzyltriethylammoniumHCID 86749985HCID 86749985, compound

Product 1

HCID 88282627HCID 88282627, compound

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

1.8 g (10 mmoles) of 2-hydroxyiminomethyl-phenylacetic acid are reacted with 1.50 ml of iodomethane, 5 g of potassium carbonate and 10 mg of triethylbenzylammonium (TEBA) chloride in 20 ml of anhydrous acetonitrile. The system is left for 6 hours at +80° C. and overnight at ambient temperature.

Sources & evidence

ORD record
ord-c735d32531ef4eea82c7e2c516d65b43
Source dataset
uspto-grants-1996_11
Patent number
US05574153

Reaction notes

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