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HRID1901206

反应详情

EQUATION

反应方程式

HRID 1901206 的结构方程式

REACTANTS

反应物

3
结构：c1c[nH]cn1
HCID795

Imidazole

C3H4N2

结构：CC(C)(C)[Si](C)(C)Cl
HCID28928

Chloro(1,1-dimethylethyl)dimethylsilane

C6H15ClSi

结构：CCOC(=O)[C@@H](O)c1ccccc1
HCID6951557

未命名化合物

PRODUCTS

生成物

1
结构：CCOC(=O)[C@@H](O[Si](C)(C)C(C)(C)C)c1ccccc1
HCID10968419

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CN(C)C=O
溶剂HCID6228

N,N-Dimethylformamide

C3H7NO

2 次

PROCEDURE

实验过程

Following a procedure similar to that described in Preparation 23, but using 23.8 g of ethyl (S)-(+)-mandelate, 26.6 g of imidazole, 400 ml of dimethylformamide, 30.1 g of t-butyldimethylsilyl chloride and 100 ml of dimethylformamide, the title compound was obtained as a liquid, boiling at 125.5°/3.0 mmHg (400 Pa).

WORKUP

后处理

  1. customthat described in Preparation 23