Diethyl Malonate → HCID 12509451, compound

HRID 1902366Notes

Reaction equation

HRID 1902366 reaction equation
[Cl:1][CH2:2][C:3](=O)[CH:4]=[CH:5][Cl:6].[C:8]([O:16][CH2:17][CH3:18])(=[O:15])[CH2:9][C:10]([O:12][CH2:13][CH3:14])=[O:11]>>[C:8]([C:9](=[C:3]([CH2:2][Cl:1])/[CH:4]=[CH:5]/[Cl:6])[C:10]([O:12][CH2:13][CH3:14])=[O:11])([O:16][CH2:17][CH3:18])=[O:15]

Participants

3

Reactant 2

HCID 7761Diethyl MalonateHCID 53421801HCID 53421801, compound

Product 1

HCID 12509451HCID 12509451, compoundYield 76.9%

Procedure

1,4-Dichloro-3-buten-2-one (0.0556 kg, 0.4 mole) and diethyl malonate (0.064 kg, 0.4 mole) were condensed under identical conditions to those described in Example 1(b) to give the title compound 0.0865 kg (77%; purity, g.l.c., 87.85%).

Workup

  1. customcondensed under identical conditions to

Sources & evidence

ORD record
ord-b30f4203052a4456ba4fa70c3e9da280
Source dataset
uspto-grants-1982_12
Patent number
US04362880

Reaction notes

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