Allylamine → HCID 12881158, compound

HRID 1902592Notes

Reaction equation

HRID 1902592 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([O:10][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)=[CH:6][C:5]=1OC1C=CC=CC=1)([O-:3])=[O:2].[CH2:24]([NH2:27])[CH:25]=[CH2:26]>O1CCCC1>[O:10]([C:7]1[CH:6]=[C:5]([C:4]([N+:1]([O-:3])=[O:2])=[CH:9][CH:8]=1)[NH:27][CH2:24][CH:25]=[CH2:26])[C:11]1[CH:12]=[CH:13][CH:14]=[CH:15][CH:16]=1

Participants

4

Reactant 2

HCID 7853AllylamineHCID 14653466HCID 14653466, compound

Product 1

HCID 12881158HCID 12881158, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

A mixture of 10 gm of 4-nitro-1,3-diphenoxy-benzene, 30 ml of tetrahydrofuran and 10 l ml of allylamine was refluxed for 8 hours. Thereafter, the reaction mixture was worked up as in Example 3, and the reaction product was recrystallized from ethanol, yielding 6.1 gm (69% of theory) of the thin-layer chromatographically (cyclohexane/toluene=1:1) uniform title compound, m.p. 67°-68° C.

Workup

  1. temperaturewas refluxed for 8 hours
  2. customthe reaction product was recrystallized from ethanol

Sources & evidence

ORD record
ord-e7449ea425b64f889dd50c031b4b6805
Source dataset
uspto-grants-1982_12
Patent number
US04364875

Reaction notes

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