Diethanolamine → Methoxyethyldiethanolamine

HRID 1903387Notes

Reaction equation

HRID 1903387 reaction equation
[CH2:1]([N:4]([CH2:8][CH2:9][OH:10])[CH2:5][CH2:6][OH:7])[CH:2]=C.N(CCO)C[CH2:13][OH:14].S(C1C=CC(C)=CC=1)(OCCOC)(=O)=O.C(=O)([O-])[O-].[Na+].[Na+]>>[CH3:13][O:14][CH2:2][CH2:1][N:4]([CH2:8][CH2:9][OH:10])[CH2:5][CH2:6][OH:7]

Participants

5

Reactant 4

HCID 8113DiethanolamineHCID 10340Sodium CarbonateHCID 41439N-Allyl-2,2'-iminodiethanolHCID 86977Ethanol, 2-methoxy-, 1-(4-methylbenzenesulfonate)

Product 1

HCID 13635719Methoxyethyldiethanolamine

Procedure

The above named compound was prepared by the procedure described in Example 1 for N-allyldiethanolamine, using 0.5 mol of diethanolamine, 0.55 mol of 2-methoxyethyl tosylate and 29.15 g of sodium carbonate. After workup the crude product was fractionally distilled and the fraction boiling from 90°-110° at 0.1 mm was collected. N-(2-Methoxyethyl)diethanolamine, i.e.,

Workup

  1. customwas prepared by the procedure
  2. distillationwas fractionally distilled
  3. customboiling from 90°-110° at 0.1 mm
  4. customwas collected

Sources & evidence

ORD record
ord-08189a7f83094e9997ab30e056d35700
Source dataset
uspto-grants-1984_03
Patent number
US04436664

Reaction notes

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