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HRID1904492

反应详情

EQUATION

反应方程式

HRID 1904492 的结构方程式

REACTANTS

反应物

2
结构：COS(=O)(=O)c1ccc(C)cc1
HCID6645

Methyl toluene-4-sulfonate

C8H10O3S

结构：Clc1ccc(P(c2ccc(Cl)cc2)c2ccc(Cl)cc2)cc1
HCID70874

Tris(4-chlorophenyl)phosphine

C18H12Cl3P

PRODUCTS

生成物

1
结构：C[P+](c1ccc(Cl)cc1)(c1ccc(Cl)cc1)c1ccc(Cl)cc1.Cc1ccc(S(=O)(=O)[O-])cc1
HCID20039277

未命名化合物

收率 91.7%

PROCEDURE

实验过程

A mixture of 2.08 g (5.69 mmol) of tris(4-chlorophenyl)phosphine and 1.03 g (5.53 mmol) of methyl tosylate was allowed to react for 1 hr at 125° C. A total of 2.80 g (5.07 mmol, 91.7%) of product was obtained, which was further purified by recrystallization from 97:3 toluene-ethanol. Analyses: mp 176.5°-177.5° C.

WORKUP

后处理

  1. customto react for 1 hr at 125° C