HRID1904494

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID6645

Methyl toluene-4-sulfonate

C8H10O3S

反应SMILES：FC(F)(F)c1ccc(P(c2ccc(C(F)(F)F)cc2)c2ccc(C(F)(F)F)cc2)cc1

HCID139448

Tris[4-(trifluoromethyl)phenyl]phosphane

C21H12F9P

PRODUCTS

产物

反应SMILES：C[P+](c1ccc(C(F)(F)F)cc1)(c1ccc(C(F)(F)F)cc1)c1ccc(C(F)(F)F)cc1.Cc1ccc(S(=O)(=O)[O-])cc1

HCID20039305

未命名化合物

收率 73.4%

PROCEDURE

实验过程

A mixture of 5.25 g (11.3 mmol) of tris(4-trifluoromethylphenyl)phosphine and 2.43 g (13.0 mmol) of methyl tosylate were allowed to react for 2 hr at 135° C. A total of 5.41 g (8.29 mmol, 73.4%) of product was obtained, which was further purified by recrystallization from toluene-ethanol. Analyses: mp 185.0°-185.8° C.

WORKUP

后处理

customto react for 2 hr at 135° C

来源与证据

来源类型: Open Reaction Database
ORD记录: ord-de26e74edf8e4eef9516fe23e927b129
来源数据集: uspto-grants-1989_06
DOI: 10.6084/m9.figshare.5104873.v1
专利号: US04837392
来源说明: uspto-grants-1989_06

反应SMILES

[F:1][C:2]([F:31])([F:30])[C:3]1[CH:8]=[CH:7][C:6]([P:9]([C:20]2[CH:25]=[CH:24][C:23]([C:26]([F:29])([F:28])[F:27])=[CH:22][CH:21]=2)[C:10]2[CH:15]=[CH:14][C:13]([C:16]([F:19])([F:18])[F:17])=[CH:12][CH:11]=2)=[CH:5][CH:4]=1.[S:32]([C:37]1[CH:43]=[CH:42][C:40]([CH3:41])=[CH:39][CH:38]=1)([O:35][CH3:36])(=[O:34])=[O:33]>>[S:32]([C:37]1[CH:43]=[CH:42][C:40]([CH3:41])=[CH:39][CH:38]=1)([O-:35])(=[O:34])=[O:33].[CH3:36][P+:9]([C:6]1[CH:5]=[CH:4][C:3]([C:2]([F:1])([F:30])[F:31])=[CH:8][CH:7]=1)([C:20]1[CH:25]=[CH:24][C:23]([C:26]([F:29])([F:27])[F:28])=[CH:22][CH:21]=1)[C:10]1[CH:15]=[CH:14][C:13]([C:16]([F:18])([F:19])[F:17])=[CH:12][CH:11]=1