HRID1913248

反应详情

EQUATION

反应方程式

HRID 1913248 的结构方程式

AUXILIARIES

试剂、催化剂与溶剂

2

CONDITIONS

反应条件

温度
45 °C

PROCEDURE

实验过程

A mixture of tert-butyl 4-(7-(bis((2-(trimethylsilyl)ethoxy)methyl)amino)pyrazolo[1,5-a]pyrimidin-5-yl)-5,6-dihydropyridine-1(2H)-carboxylate (Int-9e, 5.05 g) and 10% Pd/C (300 mg) in EtOAc was stirred at 45° C. under hydrogen (balloon pressure) for three hours. After filtration and concentration, tert-butyl 4-(7-(bis((2-(trimethylsilyl)ethoxy)methyl)amino)pyrazolo[1,5-a]pyrimidin-5-yl)piperidine-1-carboxy late (Int-9f) (5.1 g) was obtained as an oil. LC/MS: m/z=578.3 (M+H+).

WORKUP

后处理

  1. filtrationAfter filtration and concentration