Potassium Cation → 7-Bromo-1,2,3,4-tetrahydropyrazino[1,2-a]indole

HRID 192985Notes

Reaction equation

HRID 192985 reaction equation
[Al+3:20].[Br:1][c:2]1[cH:3][cH:4][c:5]2[cH:6][c:7]([C:14]([O:15][CH2:16][CH3:17])=[O:18])[n:8]([CH2:11][C:12]#[N:13])[c:9]2[cH:10]1.[C:25]([CH:26]([CH:27]([C:28]([O-:29])=[O:30])[OH:31])[OH:32])([O-:33])=[O:34].[CH3:37][CH2:38][O:39][C:40](=[O:41])[CH3:42].[H-:19].[H-:22].[H-:23].[H-:24].[K+:35].[Li+:21].[Na+:36]>>[Br:1][c:2]1[cH:3][cH:4][c:5]2[cH:6][c:7]3[n:8]([c:9]2[cH:10]1)[CH2:11][CH2:12][NH:13][CH2:14]3

Participants

9

Reactant 8

HCID 813Potassium CationHCID 923Sodium ionHCID 8857Ethyl AcetateHCID 28486Lithium ionHCID 104727Aluminum CationHCID 166653Hydride4×HCID 38061142,3-DihydroxybutanedioateHCID 21868726Ethyl 6-bromo-1-cyanomethylindole-2-carboxylate

Product 1

HCID 218687617-Bromo-1,2,3,4-tetrahydropyrazino[1,2-a]indole

Sources & evidence

ORD record
ord-46673bb6eb9f462ba58ba0344a00a54a
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (6/10)

Reaction notes

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