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HRID1930846

反应详情

EQUATION

反应方程式

HRID 1930846 的结构方程式

REACTANTS

反应物

2
结构：COC(OC)N(C)C
HCID78373

Methanamine, 1,1-dimethoxy-N,N-dimethyl-

C5H13NO2

结构：Cc1c([N+](=O)[O-])cccc1C(F)(F)F
HCID81171

alpha,alpha,alpha-Trifluoro-3-nitro-o-xylene

C8H6F3NO2

PRODUCTS

生成物

1
结构：CN(C)/C=C/c1c([N+](=O)[O-])cccc1C(F)(F)F
HCID57753441

未命名化合物

收率 83%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CN(C)C=O
溶剂HCID6228

N,N-Dimethylformamide

C3H7NO

PROCEDURE

实验过程

A solution of 17 mmol 2-methyl-3-nitrobenzotrifluoride and 43 mmol N,N-dimethylformamide-dimethylacetal in 30 ml N,N-dimethylformamide was hold at 120° C. overnight. The reaction mixture is concentrated in vacuo to give the crude title compound. Yield 83%. MS (m/e): 261.1 ([M+H]+, 90%).

WORKUP

后处理

  1. customat 120° C.
  2. customovernight
  3. concentrationThe reaction mixture is concentrated in vacuo