HRID1936531

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID6547

Azobisisobutyronitrile

C8H12N4

HCID7923

2,5-Furandione

C4H2O3

HCID97965

Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid

C9H10O4

HCID12033823

2-Hydroxyethyl bicyclo[2.2.1]hept-5-ene-2-carboxylate

C10H14O3

结构：CC(C)(C)OC(=O)C1C2C=CC(C2)C1C(=O)OC(C)(C)C

HCID21922317

未命名化合物

PRODUCTS

生成物

结构：CC(C)(C)OC(=O)C1C2C=CC(C2)C1C(=O)OC(C)(C)C.O=C(O)C1C2C=CC(C2)C1C(=O)O.O=C(OCCO)C1CC2C=CC1C2.O=C1C=CC(=O)O1

HCID131723220

未命名化合物

收率 31%

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID8028

Tetrahydrofuran

C4H8O

CONDITIONS

反应条件

温度: 67 °C

PROCEDURE

实验过程

Di-tert-butyl 5-norbornene-2,3-dicarboxylate (0.85 mole), 2-hydroxyethyl 5-norbomene-2-carboxylate (0.1 mole), 5-norbornene-2,3-dicarboxylic acid (0.05 mole) and maleic anhydride (1 mole) were mixed together in tetrahydrofuran solvent, and AIBN (5.5 g) was added to the mixture as a polymerization initiator. Polymerization was performed under nitrogen atmosphere for 10 hours while maintaining the temperature at 67° C. When the polymerization was completed, the polymer was precipitated from ethyl ether and dried in vacuo to obtain pure poly(di-tert-butyl 5-norbornene-2,3-dicarboxylate/2-hydroxyethyl 5-norbomene-2-carboxylate/5-norbomene-2,3-dicarboxylic acid/maleic anhydride) of Chemical Formula 102 shown above (yield: 31%).

WORKUP

后处理

customPolymerization
customthe polymer was precipitated from ethyl ether
customdried in vacuo

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-cfcd4e982b184ff0a6b8ca716104163c
来源数据集: uspto-grants-2002_05
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06391518B1
来源说明: uspto-grants-2002_05

反应 SMILES

[CH:1]12[CH2:7][CH:4]([CH:5]=[CH:6]1)[CH:3]([C:8]([O:10][C:11]([CH3:14])([CH3:13])[CH3:12])=[O:9])[CH:2]2[C:15]([O:17][C:18]([CH3:21])([CH3:20])[CH3:19])=[O:16].[CH:22]12[CH2:28][CH:25]([CH:26]=[CH:27]1)[CH2:24][CH:23]2[C:29]([O:31][CH2:32][CH2:33][OH:34])=[O:30].[CH:35]12[CH2:41][CH:38]([CH:39]=[CH:40]1)[CH:37]([C:42]([OH:44])=[O:43])[CH:36]2[C:45]([OH:47])=[O:46].[C:48]1(=[O:54])[O:53][C:51](=[O:52])[CH:50]=[CH:49]1.CC(N=NC(C#N)(C)C)(C#N)C>O1CCCC1>[CH:4]12[CH2:7][CH:1]([CH:6]=[CH:5]1)[CH:2]([C:15]([O:17][C:18]([CH3:19])([CH3:20])[CH3:21])=[O:16])[CH:3]2[C:8]([O:10][C:11]([CH3:14])([CH3:13])[CH3:12])=[O:9].[CH:22]12[CH2:28][CH:25]([CH:26]=[CH:27]1)[CH2:24][CH:23]2[C:29]([O:31][CH2:32][CH2:33][OH:34])=[O:30].[CH:35]12[CH2:41][CH:38]([CH:39]=[CH:40]1)[CH:37]([C:42]([OH:44])=[O:43])[CH:36]2[C:45]([OH:47])=[O:46].[C:51]1(=[O:52])[O:53][C:48](=[O:54])[CH:49]=[CH:50]1