4-Fluorobenzyl chloride → HCID 11447904, compound

HRID 1937086Notes

Reaction equation

HRID 1937086 reaction equation
[F:1][C:2]1[CH:9]=[CH:8][C:5]([CH2:6]Cl)=[CH:4][CH:3]=1.[Cl:10][SiH:11]([Cl:13])[Cl:12]>[Cl-].C([P+](CCCC)(CCCC)CCCC)CCC>[F:1][C:2]1[CH:9]=[CH:8][C:5]([CH2:6][Si:11]([Cl:13])([Cl:12])[Cl:10])=[CH:4][CH:3]=1

Participants

4

Reactant 2

HCID 96024-Fluorobenzyl chlorideHCID 24811Trichlorosilane

Product 1

HCID 11447904HCID 11447904, compoundYield 82%

Reagents, catalysts & solvents 1

HCID 75311Tetrabutylphosphonium chlorideCatalyst

Procedure

In the same apparatus and procedure as Example 1 above, 0.20 g (0.68 mmol) of tetrabutylphosphonium chloride, 1.00 g (6.92 mmol) of 4-fluorobenzyl chloride, and 2.80 g (20.7 mmol) of trichlorosilane were reacted at 130° C. for 4 hrs. The resulting mixture was distilled to give 1.19 g of (4-fluorobenzyl)trichlorosilane (82%).

Workup

  1. distillationThe resulting mixture was distilled

Sources & evidence

ORD record
ord-cc953098e8b94f31bded03add6759ef6
Source dataset
uspto-grants-2002_05
Patent number
US06392077B1

Reaction notes

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