Pyridine → HCID 86583726, compound

HRID 1937723Notes

Reaction equation

HRID 1937723 reaction equation
[N:1]1C=CC=CC=1.[C:7](Cl)(=[O:11])[C:8](Cl)=[O:9].[CH2:13]([O:17][C:18](=[O:20])[OH:19])[CH:14]([CH3:16])[CH3:15].N1CCC1=O>C(#N)C>[CH2:13]([O:17][C:18](=[O:19])[OH:20])[CH:14]([CH3:16])[CH3:15].[C:7]1(=[O:11])[NH:1][C:8]1=[O:9]

Participants

5

Reactant 3

HCID 1049PyridineHCID 65578Oxalyl chlorideHCID 86583727HCID 86583727, compound

Product 1

HCID 86583726HCID 86583726, compound

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

Pyridine was added to a solution of pNB oxalylchloride in acetonitrile. After 20 minutes the TES azetidinone isobutyl carbonate was added. The reaction was given an aqueous work up, the organics were concentrated in vacuo to afford TES oxalimide isobutyl carbonate (15.2 g) as a white solid.

Workup

  1. concentrationthe organics were concentrated in vacuo

Sources & evidence

ORD record
ord-a4063cc4a3c44028911bb8ab94781ef6
Source dataset
uspto-grants-2002_05
Patent number
US06395894B2

Reaction notes

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