反应详情

Hydroxylamine hydrochloride (0.90 g, 12.9 mmol) was added to a solution of triethylamine (1.79 mL, 12.9 mmol) in 50% ethanol/water (4 mL) and the mixture was stirred for 2 minutes. Tridecane nitrile (2.02 g, 10.4 mmol) in ethanol (10 mL) was added and the mixture refluxed for 2 hours, allowed to cool, and poured into water (50 mL). The precipitate was collected, stirred with hexanes, and filtered to yield a white solid (0.63 g, 26%). EI+ 229, 196, 85, 74.

1. temperaturethe mixture refluxed for 2 hours
2. temperatureto cool
3. customThe precipitate was collected
4. stirringstirred with hexanes
5. filtrationfiltered