Nonan-5-ol → 5-Nonanone

HRID 1945246Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1945246
IC1C=CC=CC=1S(O)(=O)=O.OOS([O-])=O.[K+].[CH3:18][CH2:19][CH2:20][CH2:21][CH:22]([OH:27])[CH2:23][CH2:24][CH2:25][CH3:26]>[N+](C)([O-])=O>[CH3:18][CH2:19][CH2:20][CH2:21][C:22](=[O:27])[CH2:23][CH2:24][CH2:25][CH3:26]

Komponenten

5

Edukt 3

HCID 12202Nonan-5-olHCID 27782472-iodobenzenesulfonic AcidHCID 23707502Potassium hydroxy sulfite

Produkt 1

HCID 104055-Nonanone

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6375NitromethaneLösungsmittel

Reaktionsbedingungen

Temperatur
70 °C

Versuchsvorschrift

1.7 mg (0.006 mmol) of 2-iodobenzenesulfonic acid, prepared by Preparation Example 1, 1.11 g (1.8 mmol) of powdered Oxone (registered trademark) and 433 mg (3 mmol) of 5-nonanol were added to 3.75 ml of nitromethane, and the mixture was heated at 70° C. while being stirred for 7.5 hours. The later treatment was carried out in the same way as in Example 1, and then 5-nonanone was obtained. The yield of the obtained 5-nonanone was determined and the result is shown in Table 1.

Quellen und Nachweise

ORD-Eintrag
ord-ee37b432431a48e68c72e42bbe0dc518
Quelldatensatz
uspto-grants-2013_03
Patentnummer
US08394995B2

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