Carbon tetrabromide → 6-Bromo-pentadecane

HRID 1950695Notes

Reaction equation

HRID 1950695 reaction equation
[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH:6](O)[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15].C(Br)(Br)(Br)[Br:18].C1(P(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1>ClCCl>[Br:18][CH:6]([CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15])[CH2:5][CH2:4][CH2:3][CH2:2][CH3:1]

Participants

5

Reactant 3

HCID 11205Carbon tetrabromideHCID 11776TriphenylphosphineHCID 989746-Pentadecanol

Product 1

HCID 866397806-Bromo-pentadecaneYield 86%

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

The title compound (13.87 g) was prepared from Pentadecan-6-ol (Example 11, 12.65 g), carbon tetrabromide (22 g), triphenylphosphine (24.82 g) and dichloromethane (200 ml) using the procedure of Example 6.

Sources & evidence

ORD record
ord-ea44599a986743be86af6014eb357e0f
Source dataset
uspto-grants-2013_03
Patent number
US08404627B2

Reaction notes

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