HRID1955826

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID1017

Phthalic acid

C8H6O4

HCID7488

1,4-Benzenedicarbonyl dichloride

C8H4Cl2O2

HCID7835

Epichlorohydrin

C3H5ClO

HCID11164

Glycidol

C3H6O2

PRODUCTS

生成物

HCID23600

Isophthalic diglycidyl ester

C14H14O6

HCID62629

1,2-Diglycidyl phthalate

C14H14O6

HCID111271

Diglycidyl terephthalate

C14H14O6

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID1140

Toluene

C7H8

溶剂HCID8471

Triethylamine

C6H15N

PROCEDURE

实验过程

Diglycidyl isophthalate and diglycidyl orthophthalate were prepared by caustic treatment of the products from the catalytic reaction of the corresponding phthalic acid with an excess of epichlorohydrin. Diglycidyl terephthalate was prepared in toluene from terephthaloyl chloride, glycidol, and triethylamine.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-96a7873b39fe4c5a92f5146df65224dd
来源数据集: uspto-grants-1998_07
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05777045
来源说明: uspto-grants-1998_07

反应 SMILES

[C:1]([OH:12])(=[O:11])[C:2]1[C:3](=[CH:7][CH:8]=[CH:9][CH:10]=1)[C:4]([OH:6])=[O:5].[CH2:13]([CH:15]1[O:17][CH2:16]1)Cl.[C:18](Cl)(=[O:28])[C:19]1[CH:27]=[CH:26][C:22]([C:23](Cl)=[O:24])=[CH:21][CH:20]=1.[CH2:30]1[O:32][CH:31]1[CH2:33][OH:34]>C1(C)C=CC=CC=1.C(N(CC)CC)C>[C:4]([O:6][CH2:26][CH:22]1[O:24][CH2:23]1)(=[O:5])[C:3]1[CH:2]=[CH:10][CH:9]=[C:8]([C:16]([O:34][CH2:33][CH:31]2[O:32][CH2:30]2)=[O:17])[CH:7]=1.[CH2:16]1[O:17][CH:15]1[CH2:13][O:5][C:4]([C:3]1[C:2]([C:1]([O:12][CH2:20][CH:19]2[O:28][CH2:18]2)=[O:11])=[CH:10][CH:9]=[CH:8][CH:7]=1)=[O:6].[C:18]([O:34][CH2:33][CH:31]1[O:32][CH2:30]1)(=[O:28])[C:19]1[CH:27]=[CH:26][C:22]([C:23]([O:5][CH2:13][CH:15]2[O:17][CH2:16]2)=[O:24])=[CH:21][CH:20]=1