Azobisisobutyronitrile → HCID 86752911, compound

HRID 1956821Notes

Reaction equation

HRID 1956821 reaction equation
[C:1]1([SH:7])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH2:8]([Si:11]([CH3:14])([Cl:13])[Cl:12])C=C.CC(N=NC(C#N)(C)C)(C#N)C>>[S:7]1[CH:1]=[CH:6][CH:5]=[C:4]1[CH2:3][CH2:2][CH2:8][Si:11]([CH3:14])([Cl:13])[Cl:12]

Participants

4

Reactant 3

HCID 6547AzobisisobutyronitrileHCID 7969ThiophenolHCID 746411873-92-3

Product 1

HCID 86752911HCID 86752911, compoundYield 88%

Conditions

Temperature
60 °C

Procedure

26.8 g thiophenol, 18.8 g allyl (methyl) dichlorosilane and 0.60 mg azobisisobutylonitrile were put in a 100-mL three-neck flask that had been subjected to nitrogen substitution and the mixture was heated at 60° C. for 5 hours. After the reaction, the product was distilled under reduced pressure, obtaining 3-(thiophenyl) propyl (methyl) dichlorosilane with a 88% yield.

Workup

  1. customAfter the reaction
  2. distillationthe product was distilled under reduced pressure

Sources & evidence

ORD record
ord-7b2980dbc6644da791257e99fba04db0
Source dataset
uspto-grants-1998_07
Patent number
US05780661

Reaction notes

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