3-Phenylprop-2-Enal → Benzenepropanal

HRID 1957769Notes

Reaction equation

HRID 1957769 reaction equation
[CH:1](=[O:10])[CH:2]=[CH:3][C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1.C([O-])(=O)C.[K+]>[Pd].O>[C:4]1([CH2:3][CH2:2][CH:1]=[O:10])[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1

Participants

5

Reactant 2

HCID 3073-Phenylprop-2-EnalHCID 517044Potassium Acetate

Product 1

HCID 7707Benzenepropanal

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 962WaterSolvent

Procedure

hydrogenating cinnamaldehyde using a Pd-containing catalyst, said hydrogenation being carried out in the presence of potassium acetate, and in the presence of 1-wt. % water, and said hydrogenation being carried out in the absence of a solvent, whereby 3-phenylpropanal is obtained;

Sources & evidence

ORD record
ord-524c6bac29ac4b24b543dbd5a1aea79d
Source dataset
uspto-grants-1998_07
Patent number
US05786507

Reaction notes

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