Hydroxylamine → HCID 178485197, compound

HRID 1974196Notes

Reaction equation

HRID 1974196 reaction equation
CS[C:3](=[N:12][CH3:13])[N:4]([C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)[CH3:5].[NH2:14][OH:15].Cl.NO>>[C:6]1([N:4]([CH3:5])[C:3]([NH:12][CH3:13])=[N:14][OH:15])[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1

Participants

4

Reactant 3

HCID 787HydroxylamineHCID 443297Hydroxyamine hydrochlorideHCID 12377317Methyl N,N'-dimethyl-N-phenylcarbamimidothioate

Product 1

HCID 178485197HCID 178485197, compound

Procedure

The above compound is also made by the reaction of S-methyl-N-phenyl-N,N'-dimethylisothiourea (3.3g, 0.017 mol) with hydroxylamine (0.088 mol) generated from hydroxylamine hydrochloride (5.86g, 0.088 mol) as in Example 1. The compound was confirmed by comparison of its NMR and thin layer chromatographic Rf values with a previously prepared compound. The yield was calculated to be about 1%.

Sources & evidence

ORD record
ord-1c76a4dad9374d4bb06ebcaa78d8c7a6
Source dataset
uspto-grants-1976_12
Patent number
US04000196

Reaction notes

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