Hydrogen Peroxide → HCID 131722537, compound

HRID 1976330Notes

Reaction equation

HRID 1976330 reaction equation
[CH3:1][C:2]([O:5][CH3:6])([CH3:4])[CH3:3].[OH:7][S:8]([OH:11])(=[O:10])=[O:9].[OH:12][OH:13]>O>[CH3:1][C:2]([O:5][CH3:6])([CH3:4])[CH3:3].[OH:10][S:8]([OH:11])(=[O:9])=[O:7].[OH:12][OH:13].[OH2:5]

Participants

5

Reactant 3

HCID 784Hydrogen PeroxideHCID 1118Sulfuric AcidHCID 15413tert-Butyl methyl ether

Product 1

HCID 131722537HCID 131722537, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Into a 250 ml round bottom three neck flask (equipped with an agitator, thermometer, and pressure equalizing addition funnel), 40 g MTBE was placed; and sufficient H2SO4 aqueous solution, H2O2 (as 60% solution in water) and water were added to provide a mole ratio of MTBE/H2SO4/H2O2/H2O of 2.15/1.3/1.0/6.3. The mixture was stirred at 50° C. two hours. When the reaction time was up, the reaction mixture was cooled down to 20° C., and transferred to a tared 250 ml separatory funnel. The aqueous phase was removed. The product was neutralized to pH 7 with 25% NaOH in order to remove residual acid and hydrogen peroxide, after which the aqueous phase was removed and the product was washed 2-3 times with 150 ml cold water, weighed and analyzed. DTBP was obtained in 75.4% yield at a purity of 87.0%.

Workup

  1. customInto a 250 ml round bottom three neck flask (equipped with an agitator

Sources & evidence

ORD record
ord-4273e8b1b443400db5e1e357836c096d
Source dataset
uspto-grants-2001_05
Patent number
US06225510B1

Reaction notes

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