1,1,1,3,3,3-Hexafluoro-2-propanol → 1,1,1,2,3,3,3-Heptafluoropropane

HRID 1978251Notes

Reaction equation

[CH:1](O)([C:6]([F:9])([F:8])[F:7])[C:2]([F:5])([F:4])[F:3].[F:11]F>>[F:3][C:2]([F:5])([F:4])[CH:1]([F:11])[C:6]([F:9])([F:8])[F:7]

Participants

Reactant 2

HCID 135291,1,1,3,3,3-Hexafluoro-2-propanol

HCID 24524Fluorine

Product 1

HCID 679401,1,1,2,3,3,3-HeptafluoropropaneYield 90%

Procedure

A vapor plug flow reactor ½″ diameter×3′ long Monel® pipe is fed with 1 g/min of the hexafluoro-2-propanol and 150 cc/min of elemental fluorine at ambient conditions to produce 1,1,1,2,3,3,3 heptafluoropropane in greater than 90% yield.

Sources & evidence

ORD record: ord-8091449eafa5418285f4ceb12e803ba3
Source dataset: uspto-grants-2001_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06235950B1

Reaction notes

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