Benzoic Acid → HCID 20437622, compound

HRID 1979896Notes

Reaction equation

HRID 1979896 reaction equation
[O-2:1].[Mg+2:2].[Cl:3][C:4]1[CH:13]=[CH:12][C:7]([C:8]([O:10][OH:11])=[O:9])=[CH:6][CH:5]=1.[C:14]([OH:22])(=[O:21])[C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1>C(OCC)(=O)C.O>[OH2:9].[OH2:21].[OH2:1].[OH2:9].[Cl:3][C:4]1[CH:13]=[CH:12][C:7]([C:8]([O:10][O-:11])=[O:9])=[CH:6][CH:5]=1.[C:14]([O-:22])(=[O:21])[C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1.[Mg+2:2]

Participants

6

Reactant 3

HCID 243Benzoic AcidHCID 70299p-Chloroperbenzoic acidHCID 6850729Magnesium monoxide

Product 1

HCID 20437622HCID 20437622, compound

Reagents, catalysts & solvents 2

HCID 962WaterSolventHCID 8857Ethyl AcetateSolvent

Procedure

Magnesium oxide (0.443 g, 11.0 mmol) was added to a solution of 4-chloroperoxybenzoic acid (94.6%, 2.00 g, 11.0 mmol) and benzoic acid (1.26 g, 10.3 mmol) in 65 mL of ethyl acetate and 0.80 mL of water. After 90 min of vigorous stirring, the precipitate was collected via filtration, washed with ethyl acetate (ca. 50 mL), and vacuum dried to give 3.50 g (82% based on Mg2+) of a white powder: Anal. Calcd for C14H17ClMgO9 : C, 43.22; H, 4.40; Cl, 9.11; Mg, 6.25; O(active), 4.11. Found: C, 43.88; H, 4.07; Cl, 9.79; Mg, 6.80; O(active), 3.95.

Workup

  1. filtrationthe precipitate was collected via filtration
  2. washwashed with ethyl acetate (ca. 50 mL), and vacuum
  3. customdried
  4. customto give 3.50 g (82% based on Mg2+) of a white powder

Sources & evidence

ORD record
ord-cbeeb1d9264b4623ae3bab39c4867db8
Source dataset
uspto-grants-1984_11
Patent number
US04483781

Reaction notes

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