2-Methylthio-2-methylpropionaldoxime → 2-Methylthio-2-methylpropionaldehyde O-[N-methyl-N-(2-chloromethyl-2-propanesulfenyl)carbamoyl] oxime

HRID 1980108Notes

Reaction equation

HRID 1980108 reaction equation
[CH3:1][S:2][C:3]([CH3:8])([CH3:7])[CH:4]=[N:5][OH:6].[CH3:9][N:10]([S:14][C:15]([CH2:18][Cl:19])([CH3:17])[CH3:16])[C:11](Cl)=[O:12]>C(N(CC)CC)C>[CH3:9][N:10]([S:14][C:15]([CH2:18][Cl:19])([CH3:17])[CH3:16])[C:11]([O:6][N:5]=[CH:4][C:3]([S:2][CH3:1])([CH3:8])[CH3:7])=[O:12]

Participants

4

Reactant 2

HCID 154362-Methylthio-2-methylpropionaldoximeHCID 13363447N-methyl-N-(2-chloromethyl-2-propanesulfenyl)carbamoyl chloride

Product 1

HCID 543555702-Methylthio-2-methylpropionaldehyde O-[N-methyl-N-(2-chloromethyl-2-propanesulfenyl)carbamoyl] oxime

Reagents, catalysts & solvents 1

HCID 8471TriethylamineSolvent

Procedure

Prepared as in Example I by reacting 2-methylthio-2-methylpropionaldoxime with N-methyl-N-(2-chloromethyl-2-propanesulfenyl)carbamoyl chloride in the presence of triethylamine as an acid acceptor. The product was isolated as an oil.

Workup

  1. customPrepared as in Example I
  2. customThe product was isolated as an oil

Sources & evidence

ORD record
ord-cb56be9e95e94775b529a8b4e7f92598
Source dataset
uspto-grants-1984_11
Patent number
US04485113

Reaction notes

Loading…