Chlorosuccinimide → 1-(Chlorosulfanyl)-4-fluorobenzene

HRID 1980903Notes

Reaction equation

[F:1][C:2]1[CH:7]=[CH:6][C:5]([SH:8])=[CH:4][CH:3]=1.[Cl:9]N1C(=O)CCC1=O>>[F:1][C:2]1[CH:7]=[CH:6][C:5]([S:8][Cl:9])=[CH:4][CH:3]=1

Participants

Reactant 2

HCID 31398Chlorosuccinimide

HCID 677894-Fluorothiophenol

Product 1

HCID 126696171-(Chlorosulfanyl)-4-fluorobenzeneYield 75.7%

Procedure

Employing the procedure of Example 13, p-fluorothiophenol (5.0 g., 39 mmoles) and N-chlorosuccinimide (5.2 g., 39 mmoles) were reacted to form p-fluorobenzenesulfenyl chloride (4.8 g., oil).

Workup

customwere reacted

Sources & evidence

ORD record: ord-733e2e743cda4ba39a5aa124059be6b3
Source dataset: uspto-grants-1985_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04511575

Reaction notes

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