Hydrochloric Acid → HCID 136387260, compound

HRID 1981430Notes

Reaction equation

HRID 1981430 reaction equation
[Cl:1][C:2]1[CH:7]=[C:6]([C:8]#[N:9])[CH:5]=[CH:4][C:3]=1[OH:10].Cl.[CH2:12]([O:14]CC)C>CO>[ClH:1].[Cl:1][C:2]1[CH:7]=[C:6]([CH:8]=[N:9][O:14][CH3:12])[CH:5]=[CH:4][C:3]=1[OH:10]

Participants

5

Reactant 3

HCID 313Hydrochloric AcidHCID 3283Diethyl EtherHCID 2735739Benzonitrile, 3-chloro-4-hydroxy-

Product 1

HCID 136387260HCID 136387260, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

While being cooled in ice, a solution of 4.5 g of 2-chloro-4-cyanophenol in 50 ml of methanol was saturated with dried gaseous hydrogen chloride (HCl). The solution was left standing overnight at room temperature and mixed with 100 ml of ethyl ether to precipitate crystals which were collected by filtration to obtain 4.0 g of 2-chloro-4-methoxyiminomethylphenol hydrochloride.

Workup

  1. temperatureWhile being cooled in ice
  2. waitThe solution was left
  3. customto precipitate crystals which
  4. filtrationwere collected by filtration

Sources & evidence

ORD record
ord-029196f52b4847e39996f8baf00ee086
Source dataset
uspto-grants-1985_04
Patent number
US04514416

Reaction notes

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