Benzaldehyde → HCID 86740832, compound

HRID 1981845Notes

Reaction equation

[OH:1][CH2:2][C@@H:3]([C@H:5]([C@@H:7]([C@@H:9]([CH2:11][OH:12])[OH:10])[OH:8])[OH:6])[OH:4].[CH:13](=O)[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1.[C:21]1([CH3:29])[CH:26]=[CH:25][C:24]([CH:27]=[O:28])=[CH:23][CH:22]=1>>[CH:13](=[C:2]([OH:1])[C@@H:3]([OH:4])[C@@H:5]([OH:6])[C@H:7]([OH:8])[C@@H:9]([OH:10])[C:11](=[CH:29][C:21]1[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1)[OH:12])[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1.[CH:2](=[C:3]([OH:4])[C@@H:5]([OH:6])[C@@H:7]([OH:8])[C@H:9]([OH:10])[C@@H:11]([OH:12])[C:27](=[C:24]1[CH:25]=[CH:26][C:21]([CH3:29])=[CH:22][CH2:23]1)[OH:28])[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1.[C:21]1([CH3:29])[CH:22]=[CH:23][C:24](=[C:2]([OH:1])[C@@H:3]([OH:4])[C@@H:5]([OH:6])[C@H:7]([OH:8])[C@@H:9]([OH:10])[C:11](=[C:17]2[CH:18]=[CH:19][C:14]([CH3:13])=[CH:15][CH2:16]2)[OH:12])[CH2:25][CH:26]=1

Participants

Reactant 3

HCID 240Benzaldehyde

HCID 5780Sorbitol

HCID 77254-Methylbenzaldehyde

Product 1

HCID 86740832HCID 86740832, compound

Procedure

Sorbitol (1 mole), benzaldehyde (1 mole) and p-tolualdehyde (1 mole) were reacted by the usual method to give a 1:2:1 dibenzylidenesorbitol/benzylidene-(p-toluylidene) sorbitol/di(p-toluylidene) sorbitol mixture.

Sources & evidence

ORD record: ord-3660655cee1149f2b34f62b8746cd3bf
Source dataset: uspto-grants-1986_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04594167

Reaction notes

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