Diphenylphosphine → HCID 14007796, compound

HRID 1982254Notes

Reaction equation

HRID 1982254 reaction equation
[CH:1]([Si:3]([CH2:10][CH2:11][CH3:12])([CH2:7][CH2:8][CH3:9])[CH2:4][CH2:5][CH3:6])=[CH2:2].[C:13]1([PH:19][C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1>>[CH2:10]([Si:3]([CH2:1][CH2:2][P:19]([C:20]1[CH:21]=[CH:22][CH:23]=[CH:24][CH:25]=1)[C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)([CH2:7][CH2:8][CH3:9])[CH2:4][CH2:5][CH3:6])[CH2:11][CH3:12]

Participants

3

Reactant 2

HCID 70017DiphenylphosphineHCID 13431037Ethenyl(tripropyl)silane

Product 1

HCID 14007796HCID 14007796, compound

Procedure

The vinyl tripropyl silane was then reacted with diphenyl phosphine with u.v. initiation for 86 hours in a manner described in Example 1. The conversion was about 95%. The mixture was fractionally distilled to yield approximately 63% of the theoretical yield of the product as a clear, colorless, mobile liquid. The product distilled at 155°-156° C. at 0.10 mm.

Workup

  1. distillationThe mixture was fractionally distilled
  2. customto yield approximately 63% of the theoretical yield of the product as a clear, colorless, mobile liquid
  3. distillationThe product distilled at 155°-156° C. at 0.10 mm

Sources & evidence

ORD record
ord-1526271a15d445b8949f7e3a2c053c07
Source dataset
uspto-grants-1986_06
Patent number
US04595753

Reaction notes

Loading…