Triethylamine → 5,6,7,8-Tetrahydronaphthyl-N-methyl-N-(N'-methyl-N'-fluoroformylaminosulfenyl)carbamate

HRID 1982276Notes

Reaction equation

HRID 1982276 reaction equation
[CH3:1][N:2]([S:6][N:7]([CH3:11])[C:8]([F:10])=[O:9])[C:3](F)=[O:4].[C:12]1([OH:22])[C:21]2[CH2:20][CH2:19][CH2:18][CH2:17][C:16]=2[CH:15]=[CH:14][CH:13]=1.C(N(CC)CC)C>C1(C)C=CC=CC=1>[C:12]1([O:22][C:3](=[O:4])[N:2]([CH3:1])[S:6][N:7]([CH3:11])[C:8]([F:10])=[O:9])[C:21]2[CH2:20][CH2:19][CH2:18][CH2:17][C:16]=2[CH:15]=[CH:14][CH:13]=1

Participants

5

Reactant 3

HCID 8471TriethylamineHCID 682585,6,7,8-Tetrahydro-1-naphtholHCID 12897270bis-(N-methyl-N-fluorocarbonylamino)sulfide

Product 1

HCID 1317147175,6,7,8-Tetrahydronaphthyl-N-methyl-N-(N'-methyl-N'-fluoroformylaminosulfenyl)carbamate

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

5,6,7,8-Tetrahydronaphthyl-N-methyl-N-(N'-methyl-N'-fluoroformylaminosulfenyl)carbamate was prepared by the procedure of Example IX by reacting 9.21 g of bis-(N-methyl-N-fluorocarbonylamino)sulfide with 7.41 g of 5,6,7,8-tetrahydro-1-naphthol in 300 ml of toluene with 5.05 g of triethylamine as acid acceptor to yield 9.5 g of an oil.

Sources & evidence

ORD record
ord-ee01cffc346640c8b8a5bb26def1ce3d
Source dataset
uspto-grants-1986_06
Patent number
US04595769

Reaction notes

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