Diisopropylamine → Trimethyl((4-nitrophenyl)ethynyl)silane

HRID 198357Notes

Reaction equation

HRID 198357 reaction equation
[Br:1][c:2]1[cH:3][cH:4][c:5]([N+:8](=[O:9])[O-:10])[cH:6][cH:7]1.[CH3:11][Si:12]([CH3:13])([CH3:14])[C:15]#[CH:16].[CH:17]([NH:18][CH:19]([CH3:20])[CH3:21])([CH3:22])[CH3:23].[Cu:24][I:25]>>[c:2]1([C:16]#[C:15][Si:12]([CH3:11])([CH3:13])[CH3:14])[cH:3][cH:4][c:5]([N+:8](=[O:9])[O-:10])[cH:6][cH:7]1

Participants

5

Reactant 4

HCID 7912DiisopropylamineHCID 114661-Bromo-4-nitrobenzeneHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 66111Trimethylsilylacetylene

Product 1

HCID 4296099Trimethyl((4-nitrophenyl)ethynyl)silane

Sources & evidence

ORD record
ord-4adaf7700f5c4969bbd8047f9f8a50ca
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (6/10)

Reaction notes

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