Hydrochloric Acid → HCID 29972132, compound

HRID 1987682Notes

Reaction equation

HRID 1987682 reaction equation
CC1(C)[O:7][C@H:6]2[C@@H:8]([OH:13])[C@@H:9]([OH:12])[CH2:10][O:11][C@@H:5]2[CH2:4][O:3]1.Cl>CO>[OH:3][CH2:4][C@@H:5]1[C@@H:6]([OH:7])[C@@H:8]([OH:13])[C@@H:9]([OH:12])[CH2:10][O:11]1

Participants

4

Reactant 2

HCID 313Hydrochloric AcidHCID 57723947HCID 57723947, compound

Product 1

HCID 29972132HCID 29972132, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

To a solution of (−)-(4aR,7S,8S,8aS)-2,2-dimethyl-hexahydropyrano[3,2-d][1,3]dioxine-7,8-diol (20 mg, 0.09 mmol) in MeOH (2 mL) was added a solution of methanolic HCl (0.5 mL, prepared from 0.5 mL conc. HCl in 30 mL of MeOH). The solution was stirred for 1H at ambient temperature and concentrated in vacuo.

Workup

  1. concentrationconcentrated in vacuo

Sources & evidence

ORD record
ord-f7c24f51373c4229ba76035dcc6cebe1
Source dataset
uspto-grants-2009_06
Patent number
US07550607B2

Reaction notes

Loading…